M. Sc. Thesis
- Title: Numerical Simulation of Governing Equations of Direct-Methanol Fuel Cells.
- Advisor: Dr. Farschad Torabi.
- Graduation Date: September ?th, 2013.
- Abstract
Increasing energy consumption and global warming problem make use of renewal energies inevitable. Among these energy resources, fuel cells are interesting due to almost inexpensive raw materials and high performance. In recent years, the direct methanol fuel cell has been increasingly interested because of its low temperature over the other fuel cells, removing problems due to storage and conversion of hydrogen, ease of operating and simplicity for transportation applications. In the first section of this study, 3D modeling of DMFC is solved by use of the finite element method. The obtained results show good agreement with experimental data which are reported in their paper. In this study, a two dimensional, isothermal, steady-state model is developed for DMFC. The model is accounting for mass balances, the charge balances, electrochemical reactions and the mass transport phenomena. Diffusion and convective effects as well as crossover of methanol are considered in this model. The governing equations are solved using COMSOL software. The results are reported as methanol concentration profile and methanol flux in gas diffusion, catalyst and membrane layers; oxygen concentration profile in cathodic catalyst layer; anodic and cathodic overpotential changes through catalyst layer, and finally, the cell voltage versus different current densities. The results show that methanol concentration reduces through the layers and reaches zero in the interface of the membrane and catalyst layer. At lower methanol concentrations, the profiles have the same concentration gradient and increase through the layers as current density increases. Furthermore, anodic and cathodic overpotential increase as current density increases. Oxygen concentration decreases through catalyst cathodic layers.Faculty of Mechanical Eng. of K. N. Toosi University of Technology
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